Reactions of Transient Free Radicals Monitored by EPR Spectroscopy

9.5 GHz EPR Isotropic Spectra in Solution

Cyclobutenyl beta-scission

J. Chem. Soc. Chem. Commun. 1980, 604-605;

J. Chem. Soc. Perkin Trans. 2, 1981, 970-974.

Spiro[2.3]hex-2-yl beta-scission

J. Chem. Soc. Perkin Trans. 2, 1985, 841-846.

Bicyclo[1.1.1]pentylmethyl to 3-methylenecyclobutylmethyl to 2-allylallyl

J. Chem. Soc. Perkin Trans. 2, 1991, 1329-1333.

1,2-Silyl migration from C to N

J. Organometal. Chem. 1991, 403, C25-C28;

J. Chem. Soc. Perkin Trans. 2, 1993, 2119-2123.

Deuteroxymethylcubyl cascade rearrangement

J. Am. Chem. Soc. 1992, 114, 10730-10738.

Oxaspiro[2.3]hexylmethyl three step cascade

J. Chem. Soc. Perkin Trans. 2, 1999, 937-945.

3,5-Dimethylcyclohexadienyl beta-scission

J. Chem. Soc. Perkin Trans. 2, 2001, 1758-1764.

Release of phenyliminyl and t-butyl radicals from an oxime ester.

J. Chem. Soc. Perkin Trans. 2, 2000, 2399-2409.

Release of aryliminyl and n-butyl radicals from an oxime ester

J. Chem. Soc. Perkin Trans. 2, 2000, 2399-2409

Generation of a carbamoyl radical by beta-scission of an amidocyclohexadienyl radical

J. Chem. Soc. Perkin Trans. 2, 2002, 1839-1843.

Generation and rapid cyclisation of a carbamoyl radical

J. Chem. Soc. Perkin Trans. 2, 2002, 1839-1843.

Formation of an alkoxyaminyl radical by cyclisation of a carbamoyl radical on to an oxime ether

J. Org. Chem. 2004, 69, 5926-5933.

Generation of cyclohexadienyl and carbamoyl radicals from an amidocyclohexadiene. Subsequent cyclisation onto an oxime ether and release of triphenylmethyl radicals.

J. Org. Chem. 2004, 69, 5926-5933.

Photosensitized dissociation of an oxime oxalate amide releasing iminyl and carbamoyl radicals: the latter subsequently undergoing ring closure.

Org. Biomol. Chem. 2004, 2, 716-724.

Generation of iminyl and carbamoyl radicals from an oxime oxalate amide.

A rare 4-exo-cyclisation of the latter.

Org. Lett. 2005, 7, 155-158.

4-Exo-cyclisation of a carbamoyl radical onto an oxime ether.

Org. Lett. 2005, 7, 155-158.

Generation and beta-scission of a thioimidoyl radical

Two central lines of the t-Bu radical spectrum only.

Org. Lett. 2003, 5, 901-904

J. Org. Chem. 2004, 69, 2056-2069.

Competing cyclisation and beta-scission of a thioimidoyl radical

Org. Lett. 2003, 5, 901-904

J. Org. Chem. 2004, 69, 2056-2069.