EPR Spectroscopic Signatures of Polycyclic and Platonic Radicals

9.5 GHz Isotropic Spectra in Solution

 

Bicyclo[1.1.1]pent-1-yl  J. Chem. Soc. Chem. Commun. 1983, 900-901

 

3-Chlorobicyclo[1.1.1]pent-1-yl  J. Am. Chem. Soc. 1995, 117, 2758-2766

35-Cl indicates 35Cl-containing isotopomer, 37-Cl indicates 37Cl-containing isotopomer,   * indicates some of the lines of the Et2Si(H)CHCH3 radical.

 


 

 

Spiro[2.2]pentan-2-yl J. Chem. Soc. Perkin Trans. 2 1982, 751-757.

 

Spiro[2.3]hexan-2-yl radical  J. Chem. Soc. Perkin Trans. 2, 1985, 841-846

 

 


 


 

Spiro[3.3]heptan-2-yl  J. Chem. Soc. Perkin Trans. 2, 1986, 305-311.

High field half spectrum.

 

 

 

Bicyclo[2.1.1]hexan-2-yl  J. Chem. Soc. Perkin Trans. 2 1988, 1989-1993

 

Central and low field regions

 


 

 

 

Tricyclo[3.1.1.03,6]hept-6-yl  Aust. J. Chem. 1994, 47, 1285-1293.

 

* Indicates some of the lines of the Et2Si(H)CHCH3 radical.

 

 

Cubyl J. Chem. Soc. Chem. Commun. 1990, 1589-1591; J. Am. Chem. Soc. 1992, 114, 10730-10738

 

Homocubyl J. Am. Chem. Soc. 1994, 116, 2759-2766.


 

 

Bicyclo[2.2.2]oct-1-yl Mag. Res. Chem. 1995, 33, S53-S59